Song XIANG
,
Guoquan LIU
,
Yang LI
,
Changrong LI
,
ong WANG
,
null
,
null
,
null
,
null
,
null
材料科学技术（英）
Microalloying element Nb in low carbon steels produced by compact strip production (CSP) process plays an important role in inhibiting recrystallization, decreasing the transformation temperature and grain refinement. With decreasing the rolling temperature, dislocations can be pinned by carbonitrides and the strength is increased. Based on the two sublattice model, with metal atom sublattice and interstitial atom sublattice, a thermodynamic model for carbonitride was established to calculate the equilibrium between matrix and carbonitride. In the steel produced by CSP, the calculation results showed that the starting temperature of precipitation of Ti and Nb are 1340℃ and 1040℃, respectively. In the range of 890-950℃, Nb rapidly precipitated. And the maximum of the atomic fraction of Nb in carbonitride was about 0.68. The morphologies and energy spectrum of the precipitates showed that (NbTi) (CN) precipitated near the dislocations. The experiment results show that Nb rapidly precipitated when the temperature was lower than 970℃, and the atomic fraction of Nb in carbonitride was about 60%-80%. The calculation results are in agreement with the experiment data. Therefore the thermodynamic model can be a useful assistant tool in the research on the precipitates in the low carbon steels produced by CSP.
关键词:
Compact strip production
,
strip
,
production
,
niobium
,
low
,
car
Min XU
,
Minxiu QUAN
,
Zhuangqi HU
,
Y
,
ong WANG
,
Liang ZUO
材料科学技术（英）
Fe62Co8-xCrxZr6Nb4B20(x=0–4 at. pct) metallic glasses show high thermal stability with a maximum supercooled liquid region of about 84.8 K. The addition of 2 at. pct Cr causes the extension of the supercooled liquid region remarkably, leading to the enhancement of thermal stability and glass-forming ability. The crystallization of the Fe-based glassy alloys takes place through a single exothermic reaction, accompanying the precipitation of more than three kinds of crystallized phases such as α-Fe, Fe2Zr and ZrB2. The long-range atomic rearrangements required for the precipitation of the multiple crystalline phases seem to play an important role in the appearance of the large supercooled liquid region through the retardation of the crystallization reactions. The Fe-based alloys exhibit soft ferromagnetic properties. The saturation magnetization decreases with increasing Cr content while the saturated magnetostriction increases as a function of Cr content. There is no distinct change in the saturation magnetization and coercive force with annealing temperature below the crystallization temperature. The devitrification gives rise to a considerable enhancement in both δs and Hc.
关键词:
Cr addition
,
null
,
null
